By Vitaly Topolov
The booklet bargains with perovskite-type ferroelectric stable options for contemporary fabrics technology and purposes, fixing difficulties of advanced heterophase/domain buildings close to the morphotropic section boundary and purposes to varied structures with morphotropic levels. during this ebook area state–interface diagrams are awarded for the translation of heterophase states in perovskite-type ferroelectric reliable ideas. It permits to explain the tension aid within the presence of polydomain stages, the habit of unit-cell parameters of coexisting levels and the impression of exterior electrical fields. the newness of the e-book is composed in (i) the 1st systematization of information approximately heterophase states and their evolution in ferroelectric sturdy ideas (ii) the overall interpretation of heterophase and area buildings at altering temperature, composition or electrical box (iii) the whole research of interconnection area buildings, unit-cell parameters alterations, heterophase constructions and rigidity relief.
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J. Appl. Phys. 44:938–944 (1973) 45. Capelle B, Malgrande C, Antiphase Domain Walls in Ferroelectric-Ferroelastic GDMO Crystals. A. , 7–10 August 1983. (New York London, 1984) pp 511–522 46. Rychetsky I, Schranz W, Antiphase boundaries in Hg2 Br2 and KSCN. J. Phys. Condens. Matter 5:1455–1472 (1993) 47. Salje EKH, Phase Transitions in Ferroelastic and Co-Elastic Crystals. (Cambridge University Press, Cambridge, New York, Oakleigh, 1990) 48. Heine V, Bratkovsky AM, Salje EKH, The effect of clamped and free boundaries on long range strain coupling in structural phase transitions.
Rev. B 12:5128–5140 (1975) 41. Vagin SV, Dudnik EF, Method of interpreting the domain structure of ferroelastics. Bull. Acad. Sci. R. Phys. Ser. 47(3):78–81 (1983) References 21 42. Shuvalov LA, Dudnik EF, Pozdeyev VG, Forbidden domain boundaries in ferroelastics. Izvestiya Akademii Nauk SSSR. Seriya Fizicheskaya 51:2119–2123 (1987) (in Russian) 43. Boulesteix C, A survey of domains and domain walls generated by crystallographic phase transitions causing a change of lattice. Physica Status Solidi (a) 86:11–42 (1984) 44.
I, II, III, IV, and V denote the Pm3m; P 4mm, Cm, R3m, and R3c phases, respectively. The hatched area represents the region of the coexistence of the P 4mm and Cm phases. 2 (reprinted from paper by Topolov and Turik [43], with permission from IOP Publishing) the formation of the ZNSP (see points 1–5 and 7 in Fig. 3) or slightly strained interphase boundaries (see points 6 and 8 in Fig. 3). The strained interphase boundaries can be in the form of planar or conic [43] surfaces with a sufficiently small curvature.